Physics for Information Science: Unit I: Electrical Properties of Materials

Effective Mass Approximation

Electrical Properties of Materials

electron moving in constant potential field m* = m.electron moving in a periodic potential m*≠m and therefore the electron in the crystal will behave as a particle with variable effective mass.

EFFECTIVE MASS APPROXIMATION

We know the energy of the electron in a uniform potential field is





............(1)

We know the effective mass of an electron moving in a periodic potential is

............(2)

Comparing equation (1) and (2), we can say that for an electron moving in constant potential field m* = m

But for an electron moving in a periodic potential m*≠m and therefore the electron in the crystal will behave as a particle with variable effective mass.

Thus when an electron is applied with periodic potential, the free electron mass (m) should be replaced by proper effective mass (m*) and this is called as effective mass approximation.

Therefore by replacing the value of m by m* in the energy value we can write the energy of an electron in a periodic potential as

............(3)

The concept of effective mass and its approximation is used for finding the high electronic specific heat of transition metals and their paramagnetic susceptibilities experimentally.

Physics for Information Science: Unit I: Electrical Properties of Materials : Tag: : Electrical Properties of Materials - Effective Mass Approximation


Physics for Information Science: Unit I: Electrical Properties of Materials



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