Physics for Information Science: Unit I: Electrical Properties of Materials

Bloch Theorem [for Reference Purpose]

Definition, Explanation, Proof, Equation | Electrical Properties of Materials

Bloch theorem is a mathematical statement of an electron wave function moving in a perfectly periodic potential. These functions are called bloch functions.

Bloch Theorem [For Reference Purpose]

Bloch Theorem

Bloch theorem is a mathematical statement of an electron wave function moving in a perfectly periodic potential. These functions are called bloch functions.

Explanation

Let us consider an electron moving in a periodic potential.

The one dimensional Schroedinger wave equation for an electron moving in a periodic potential shall be written as

............(1)

Suppose the electron moves along X-direction in a one dimensional crystal, then the potential energy of the electron should satisfy the condition

V (x) = V (x+a) ............(2)

Where a is the periodicity of the potential.

The solution for equation (1) is

Ψ (x) = eikx uk (x) .....(3)

where

uk (x) = uk (x + a) .....(4)

Here eikx represents the plane wave and uk(x) represents the periodic function.

Equation (3) is called Bloch theorem and Equation (4) is called Bloch function.

Proof

If equation (1) has the solutions with the property of equation (2), we can write the property of the Bloch functions i.e., equation (3) as

Ψ (x + a) = eik (x + a) uk (x + a)

(or) Ψ (x+ a) = eikx  eikauk (x + a)

Since uk(x+ a) = uk(x), we can write the above equation as

Ψ (x + a) = eikx eikauk (x)

Since Ψ (x) = eikx uk(x), we can write the above equation as

Ψ (x+ a) = eika Ψ (x)

(or) Ψ  (x+ a) =QΨ (x)

Where Q = eika

If Ψ (x) is a single-valued function, then

we can write Ψ  (x) = Ψ  (x+ a) Thus Bloch theorem is proved.

This equation is similar to that of eqn (2) and eqn (4) i.e., If the potential is a function of 'x' and ' a ', then the wave function is also a function of 'x' and ' a '.

Physics for Information Science: Unit I: Electrical Properties of Materials : Tag: : Definition, Explanation, Proof, Equation | Electrical Properties of Materials - Bloch Theorem [for Reference Purpose]


Physics for Information Science: Unit I: Electrical Properties of Materials



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